Product ID:D-FRUCTOSE 6-PHOSPHATE DISODIUM AMORPHOUS, F3627
MSDS Date:01/01/1999
FSC:6505
NIIN:00N092719
Status Code:A
MSDS Number: CJTST

SIGMA CHEMICAL CO

ST LOUIS, MO 63178
US

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

D-FRUCTOSE 6-PHOSPHATE DISODIUM AMORPHOUS

CAS: 26177-86-6

OSHA PEL N/K

ACGIH TLV: N/K

ETHYL ALCOHOL

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1900 MG/M3;1000 PPM

ACGIH TLV: 1880 MG/M3;1000 PPM

METHYL ALCOHOL (METHANOL)

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 260 MG/M3;200 PPM

ACGIH TLV: 262 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MATERIAL
IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
EXPOSURE CAN CAUSE CENTRAL NERVO US SYSTEM DEPRESSION,
GASTROINTESTINAL DISTURBANCES, NARCOTIC EFFECT, DAMAGE TO THE EYES,
DAMAGE TO THE LIVER, DAMAGE TO THE HEART, DAMAGE TO THE KIDNEYS.
MAY CAUSE CONVULSIONS. TARGET ORGANS: NERVES, EYES, LIVER,
KIDNEYS. THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND COPIOUS AMOUNTS OF
WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RES PIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE.

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP,
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS
COMPLETE.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health

Solubility in Water:SOLUBLE
Appearance and Odor:SOLID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE, PHOSPHOROUS OXIDES.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN
THOROUGHLY INVESTIGATED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

SARA Title III Information:MAY CONTAIN UP TO: 4.0% METHANOL #67-56-1.
THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.
Federal Regulatory Information:EUROPEAN INFORMATION: TOXIC. R 23/24/25:
TOXIC BY INHALATION, IN CONTAC WITH SKIN AND IF SWALLOWED. R
36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. S 45: IN
CASE OF ACCIDENT OR IF YOU FEE L UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). S 24: AVOID CONTACT
WITH SKIN. S 36: WEAR SUITABLE PROTECTIVE CLOTHING. TLV AND SOURCE:
FOR ETHYL ALCOHOL (ETHANOL): ACGIH TL V-TWA: 1000 PPM (1880 MG/M3).
OSHA PEL: 8H TWA 1000 PPM (1900 MG/M3). FOR METHYL ALCOHOL- SKIN:
ACGI H TLV-TWA: 200 PPM (260 MG/M3); STEL: 250 PPM (310 MG/M3).
OSHA PEL: 8H TWA 200 PPM (260 MG/M3); STEL: 250 PPM (310 MG/M3).
State Regulatory Information: